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“材化讲坛”第93讲——The new ionic additives for safer and durable electrolytes in lithium-ion batteries

2025-10-21  点击:[]

报告时间:20251022日下午300

报告地点:1#实验楼225会议室

报告人:塞尔维亚诺维萨德大学Snežana Papović教授

报告人简介Snežana Papović is an Assistant Professor of Chemistry at the University of Novi Sad, Faculty of Sciences, Department of Chemistry, Biochemistry, and Environmental Protection. Her research includes electrolytes for lithium-ion batteries, the synthesis and physicochemical study of ionic liquids, and the thermal behavior of advanced materials. She has published 78 SCI-indexed papers, maintains an H-index of 18 with over 1,000 citations, and regularly reviews articles for both national and international journals.

She leads a Serbia Science Fund project on new ionic additives for safer and more durable Li-ion electrolytes. She contributes to COST Action NECTAR and the Horizon MSCA FreeCoVer initiative, along with bilateral collaborations with China and Italy and several industry innovation-voucher projects. Her recognitions include the Serbian Chemical Society Medal for Excellence and Success in Science, the L’Oréal-UNESCO For Women in Science Fellowship, and various university and society awards for young scientists. She is Secretary and Board Member of the Section for Green Chemistry of the Serbian Chemical Society and has participated in scientific and organizing committees of national and international conferences.

报告摘要:Lithium-ion batteries are becoming increasingly important for electrifying the modern transportation system and, thus, hold the promise to enable sustainable mobility in the future. However, their large-scale application is hindered by severe safety concerns when the cells are exposed to mechanical, thermal, or electrical abuse conditions. These safety issues are intrinsically related to their superior energy density, combined with the (present) utilization of highly volatile and flammable organic-solvent-based electrolytes. Improving the thermal stability of electrolytes and the safety of LIBs is one of the imperatives of our investigations.

The challenges, which so far prevent the widespread replacement of organic carbonate-based electrolytes, will also be mentioned. Starting from rather “facile” electrolyte modifications by (partially) replacing the organic solvent or lithium salt and/or the addition of functional electrolyte additives, conceptually new electrolyte systems, including ionic liquids (ILs) are considered. Ionic liquid/organic solvent mixtures are investigated as potential optimal electrolytes for lithium-ion batteries (LIBs) that can combine low flammability, good thermal stability and high electrical conductivity. That approach provides a great chance of developing highly functionalized, new electrolyte systems, which may overcome the afore-mentioned safety concerns related to conventional electrolytes, also offering enhanced mechanical, superior thermal performance, electrochemical performance and safety tolerance to both overcharge and thermal abuse.

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